Enzyme reactor

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  • The book is intended to provide a sound basis for enzyme reactor design based on kinetic principles, and give an updated vision of the potentials and limitations of enzyme biocatalysis, especially with respect to recent applications in processes of organic synthesis. The book is structured in the form of a textbook that goes from basic principles of enzyme structure and function to reactor design for homogeneous systems with soluble enzymes, and heterogeneous systems with insolubilized enzymes.

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  • Diffusion is the transport of matter from one point to another by thermal motion of atoms or molecules. It is relatively fast in gases, slow in liquids, and very slow in solids. Diffusion plays a key rˆole in many processes as diverse as intermixing of gases and liquids, permeation of atoms or molecules through membranes, evaporation of liquids, drying of timber, doping silicon wafers to make semiconductor devices, and transport of thermal neutrons in nuclear power reactors.

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  • F-ATP synthase synthesizes ATP at the expense of ion motive forcebyarotarycouplingmechanism. Acentral shaft, subunitc, functionally connects the ion-driven rotary motor, FO, with the rotary chemical reactor, F1.Using polarized spectrophotometry we have demonstrated previ-ously the functional rotation of the C-terminala-helical portion ofcin the supposed ‘hydrophobic bearing’ formed by the (ab)3hexagon. In apparent contradiction with these spectroscopic results, an engineered disulfide bridge between thea-helixofcand subunitadidnot impair enzyme activity....

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