Ravimetric methods of analysis

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  • As currently taught, the introductory course in analytical chemistry emphasizes quantitative (and sometimes qualitative) methods of analysis coupled with a heavy dose of equilibrium chemistry. Analytical chemistry, however, is more than equilib- rium chemistry and a collection of analytical methods; it is an approach to solving chemical problems. Although discussing different methods is important, that dis- cussion should not come at the expense of other equally important topics.

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  • Colloid and surface chemistry occupy a paradoxical position among the topics of physical chemistry. These are areas which have traditionally been considered part of physical chemistry and are currently enjoying more widespread application than ever due to their relevance to environmental and biological problems. At the same time, however, colloid and surface chemistry have virtually disappeared from physical chemistry courses. These topics are largely absent from the contemporary general chemistry course as well.

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  • The prototypical catalytic reductiveC–Cbond formations, the Fischer-Tropsch reaction [1] and alkene hydroformylation [2], were discovered in 1922 and 1938, respectively [3,4]. These processes, which involve reductive coupling to carbon monoxide, have long been applied to the industrial manufacture of commodity chemicals [5]. Notably, alkene hydroformylation, also known as the oxo-synthesis, has emerged as the largest volume application of homogeneous metal catalysis, accounting for the production of over 7 million metric tons of aldehyde annually.

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