Rotational spectroscopy

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  • A new edition of any book presents an opportunity which an author welcomes for several reasons. It is a chance to respond to constructive criticisms of the previous edition which he thinks are valid. New material can be introduced which may be useful to teachers and students in the light of the way the subject, and the teaching of the subject, has developed in the intervening years. Last, and certainly not least, there is an opportunity to correct any errors which had escaped the author’s notice....

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  •  Infrared (IR) Spectroscopy: – First real IR spectra measured by Abney and Festing in 1880’s – Technique made into a routine analytical method between 1903- 1940 (especially by Coblentz at the US NBS) – IR spectroscopy through most of the 20th century is done with dispersive (grating) instruments, i.e. monochromators – Fourier Transform (FT) IR instruments become common in the 1980’s, led to a great increase in sensitivity and resolution  Raman Spectroscopy: – In 1928, C. V.

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  • (BQ) Part 2 book "Physical chemistry" has contents: Rotational and vibrational spectroscopy, electronic spectroscopy of molecules, magnetic resonance spectroscopy, statistical mechanics, experimental kinetics and gas reactions, chemical dynamics and photochemistry,...and other contents.

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  • Cordyceps gunnii (berk.) Berk (C. Gunnii) is well known as a Chinese rare caterpillar fungus and has similar pharmacological activity with C. sinensis. In this work, a high-molecular-weight polysaccharide (CPS) was isolated and purified from the mycelia of C. gunnii. The total sugar content of CPS was amounted to 92.84%. The result of HPLC indicated that CPS was a homogeneous polysaccharide. The estimated average molecular weight of CPS was 3.72 ×106 Da. The specific rotation of CPS was recorded [˛]25 D = +134.2◦.

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  • Since the advent of magnetic resonance (MR) imaging, systems with amagnetic field intensity of 1.5 tesla (T) have been deemed the gold standard for different clinical applications in all body areas. Ongoing advances in hardware and software have made theseMRsystems increasingly compact, powerful and versatile, leading to the development of higher magnetic field strength MRsystems (3.0 T) for use in clinical practice and for research purposes. As usually occurs with a new technology, 3.0 T MR imaging units will probably follow the same development trends in the years to come....

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  • O-speci®c polysaccharides (O-antigens) of the lipopolysac-charides (LPS) of Proteus penneristrains 1 and 4 were studiedusingsugaranalysis, 1 Hand13 CNMRspectroscopy, including 2D COSY, H-detected 1 H, 13 CHMQC, and rotating-frameNOE spectroscopy (ROESY). The following structures of the tetrasaccharide (strain 1) and pentasac-charide (strain 4) repeating units of the polysaccharideswere established

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