Thermodynamic properties

Harvesting microalgae by centrifugation and filtration is very costly, affecting technical and economical feasibility of downstream processing of algal biomas to bioproducts. Flocculation is a potential technique for recovery of algae biomass. Particularly, flocculation using magnetic nanoparticles offers high separation efficiency due to their high surface area and magnetic properties. I

10p dianmotminh02 03-05-2024 5 1   Download

The molecular properties of apigenin, luteolin and nevadensin which are three naturally flavonoid compounds have been studied theoretically by DFT method at 6- 311++G(d,p) level. All FMO analysis, mechanism, and kinetics studied suggested that compound luteolin (3) was a promising antioxidant agent. The results indicated that HAT is thermodynamically preferred in the gas phase, and SPLET is the thermodynamically favorable pathway in methanol and water.

11p nguaconbaynhay10 19-02-2021 18 3   Download

Thermodynamic quantities such as mean nearest neighbor distance, free energy, isothermal and adiabatic compressibilities, isothermal and adiabatic elastic modulus, thermal expansion coefficient, heat capacities at constant volume and constant pressure, and entropy of binary interstitial alloys with a body-centered cubic (BCC) structure with a very small concentration of interstitial atoms are derived using the statistical moment method.

10p tamynhan5 10-12-2020 17 3   Download

Numerical calculations of the quantities were performed for Fe and W thin films and found to be in good and reasonable agreement with other theoretical results and experimental data. This research proves that thermal expansion coefficients of thin films approach the values of bulk when thin film is about 70 nm thick.

10p tamynhan9 02-12-2020 18 1   Download

Some thermodynamic quantities of ZrxCe1-xO2/CeO2 systems are investigated by using the moment method in statistical dynamics taking into account the anharmonicity effects of lattice vibrations. The analytic expression of the Gibbs free energy, Helmholtz free energy, and specific heats at the constant volume of ZrxCe1-xO2/CeO2 systems are obtained.

11p tamynhan9 02-12-2020 12 1   Download

An examination of the first-row-transition-metal-doped boron clusters, B14M (M = Sc, Ti, V, Cr, Mn, Fe, Co, Ni, and Cu) in the neutral state, is carried out using DFT quantum chemical calculations. The lowest-energy equilibrium structures of the clusters considered are identified at the TPSSh/ 6- 311+G(d) level. The structural patterns of doped species evolve from exohedrally capped quasi-planar structure B14 to endohedrally doped double-ring tubular when M is from Sc to Cu.

7p nguaconbaynhay9 03-12-2020 13 1   Download

Thermodynamic properties of rare-earth metals have been studied using staistical moment method. The analytic expressions of the Helmholtz free energy and thermodynamic quantities were obtained. Present SMM results of nearest neighbor distance, linear thermal expansion coefficient and specific heats at constant pressure for Th and Ce metals are compared with the experimental results.

7p tamynhan8 04-11-2020 12 1   Download

Molecular crystals are characterized by strong intramolecular forces and much weaker intermolecular forces. High-pressure spectroscopic studies provide useful data for refining the various model potentials which are used to predict of the physical properties of such systems as well as for the formation of various crystalline phases.

7p tamynhan8 04-11-2020 16 2   Download

We have investigated the thermodynamic properties of the cubic zirconia ZrO2 using the statistical moment method in the statistical physics. The free energy, thermal lattice expansion coefficient, specific heats at the constant volume and those at the constant pressure, CV and CP , are derived in closed analytic forms in terms of the power moments of the atomic displacements.

16p 12120609 01-06-2020 10 1   Download

Purpose, object and scope of studying: Apply of q-deformed Fermi-Dirac statistics to research heat capacity and paramagnetic susceptibility of free electron gas in metals at low temperatures, formula of heat capacity and magnetic susceptibility from the free electron gas in a metal depends on q deformation

26p change00 04-05-2016 44 2   Download

Objectives lecture "Chapter 2 : Refrigerant" leaves: Understand the requirements of refrigerant and coolant, understand the thermodynamic and property of some refrigerants, use the refrigerant chart to display refrigeration cycle. Invite you to reference.

53p tuenguyen1981 05-02-2016 63 3   Download

A clear difference in the enthalpy changes derived from spectroscopic and calorimetric measurements has recently been shown. The exact interpretation of this deviation varied from study to study, but it was generally attributed to the non-two-state transition and heat capacity change. Although the temperature-dependent thermodynamics of the duplex formation was often implied, systemic and extensive studies have been lacking in universally assigning the appropriate thermodynamic parameter sets.

10p system191 01-06-2013 36 4   Download

A comparative study of thermodynamic and kinetic aspects of Cu(II) and Ni(II) binding at the N-terminal binding site of human and bovine serum albumins (HSA and BSA, respectively) and short peptide analogues was performed using potentiometry and spectroscopic techniques. It was found that while qualitative aspects of interaction (spectra and structures of complexes, order of reactions) could be reproduced, the quantitative parameters (stability and rate constants) could not.

9p research12 01-06-2013 38 4   Download

Heteronuclear high-resolution NMR spectroscopy was employed to determine the solution structure of the excisi-onase protein (Xis)from thek-like bacteriophage HK022 and to study its sequence-specificDNA interaction. Aswild-typeXiswas previously characterizedas a generallyunstable protein, abiologicallyactiveHK022Xismutantwithasingle amino acid substitutionCys28fiSerwas used in this work.

13p fptmusic 12-04-2013 45 3   Download

Cellobiose dehydrogenase (CDH) is an extracellular flavocytochrome con-taining flavin and b-type heme, and plays a key role in cellulose degrada-tion by filamentous fungi. To investigate intermolecular electron transfer from CDH to cytochrome c, Phe166, which is located in the cytochrome domain and approaches one of propionates of heme, was mutated to Tyr, and the thermodynamic and kinetic properties of the mutant (F166Y) were compared with those of the wild-type (WT) enzyme.

0p awards 06-04-2013 35 2   Download

NMR and visible spectroscopy coupled to redox measurements were used to determine the equilibrium thermodynamic properties of the four haems in cytochrome c3 under conditions in which the protein was bound to lig-ands, the small anion phosphate and the protein rubredoxin with the iron in the active site replaced by zinc.

10p awards 06-04-2013 37 4   Download

Heme endows human serum albumin (HSA) with heme-protein-like reactiv-ity and spectroscopic properties. Here, the kinetics and thermodynamics of reductive nitrosylation of ferric human serum heme-albumin [HSA-heme-Fe(III)] are reported. All data were obtained at 20C. At pH 5.5, HSA-heme-Fe(III) binds nitrogen monoxide (NO) reversibly, leading to the formation of nitrosylated HSA-heme-Fe(III) [HSA-heme-Fe(III)-NO].

12p mobifone23 21-01-2013 52 6   Download

Psychrometrics deals with the thermodynamic properties of moist air, which is the final heat transport medium in most air conditioning processes. The use of psychrometric tables and charts allows the designer to make a rational and graphic analysis of the desired air conditioning processes.

16p babyuni 16-08-2010 110 17   Download

The handbook includes information on thermodynamics and the properties of fluids; the three modes of heat transfer - conduction, convection, and radiation; and fluid flow, and the energy relationships in fluid systems. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility fluid systems.

0p minhhuy 14-03-2009 205 53   Download