Catechol 1

This paper presents the results of an investigation of the properties of a modified platinum electrode with meso-tetraphenylporphyrin iron(III) complex immobilized in Nafion film and its catalytic activity in the electrochemical oxidation of selected hydroquinone and catechol derivatives. The redox activity of iron complexes of porphyrins was characterized in aqueous solutions of perchloric acid by means of cyclic voltammetry and differential pulse voltammetry.

14p langthannam 29-12-2021 4 0   Download

The synthesis and characterisation including 1 H and 13 C NMR spectroscopy of a Mannich base 1,4-di-(5- acetamido-2-hydroxybenzyl)piperazine is herein reported. The Mannich reaction leading to the formation of the ligand took place at both ends of piperazine. Four metal complexes [Cu(II) and Fe(III)] including those bearing thiocyanate groups (SCN–) in N- and S-bonding modes have been studied for their abilities to mimic catecholase oxidase. All the metal complexes are catalytically active with the highest turnover rate (k cat) recorded for complex 3.

10p tudichquannguyet 29-11-2021 12 1   Download

A catechol-based benzoxazine copolymer is reported via a new approach using an oxazine-thiol reaction. The main chain benzoxazine precursor was obtained via the classic benzoxazine synthesis methodology using the raw chemicals catechol, formaldehyde, and 4,7,10-trioxa-1,13-tridecanediamine. The countercomponent was synthesized from poly(ethylene glycol) methyl ether via the Fischer esterification reaction. The obtained reactive catechol-based benzoxazine was then reacted in mild conditions with polymeric thiol precursor to obtain a copolymer structure.

14p tudichquannguyet 29-11-2021 8 1   Download

The present study aims to investigate appropriate culture conditions for enhancing the expression of the cat1 gene encoding CAT1 enzyme from Burkholderia cepacia DF4 in Escherichia coli M15. The optimized culture conditions for gene expression are cell density at the time of induction, shaking speed, induction temperature, induction time, and inducer concentration. The highest level for CAT1 was obtained at the IPTG concentration of 1.2 mM, 10 hours after induction at 35 °C, shaking speed 200 rpm with cell density at OD600 0.7.

5p nguaconbaynhay10 20-02-2021 20 2   Download

Acetaldehyde, Acrylamide, Aflatoxin, Allyl isothiocyanate, Aniline, Benzaldehyde, Benzene, Benzo(a)pyrene, Benzofuran, Benzyl acetate, Caffeic acid, Catechol, Coumarin, 1,2,5,6-dibenz(a)anthracene, Estragole, Ethyl alcohol, Ethyl acrylate, Ethyl benzene, Ethyl carbamate, Furan and furan derivatives, Furfural, Heterocyclic amines, Hydrazines Hydrogen peroxide, Hydroquinone, d-limonene, 4-methylcatechol, Methyl eugenol, Psoralens, Quercetin glycosides, Safrole While this may seem frightening, the levels of these chemicals and pesticide residues found in food are too low to affect heal...

17p cao_can 02-01-2013 60 4   Download

Hệ adrenergic là hệ hậu hạch giao cảm, giải phóng chất trung gian hóa học gọi chung là catecholamin vì đều mang nhân catechol (vòng benzen có hai nhóm OH ở vị trí ortho và một gốc amin ở chuỗi bên. Các catecholamin gồm có adrenalin (được sản xuất chủ yếu ở tuỷ thượn g thận) noradrenalin (ở đầu tận cùng các sợi giao cảm) và dopamin (ở một số vùng trên thần kinh trung ương). Hình 6.1. Sinh tổng hợp catecholamin 1. CHUYỂN HÓA CỦA CATECHOLAMIN Catecholamin được sinh tổng hợp từ tyrosin dưới tác dụng của một số enzym...

5p thaythuocvn 26-10-2010 201 19   Download