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Gas storage and separation
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Sorption of gases in micro- and mesoporous materials is typically interpreted on the basis of idealized structural models where real structure effects such as defects and disorder are absent. For covalent organic frameworks (COFs) significant discrepancies between measured and simulated adsorption isotherms are often reported but rarely traced back to their origins.
10p
vironald
15-12-2022
9
2
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The synthesis of metal-organic frameworks has attracted considerable interest due to their potential applications as functional materials in catalysis; 1,2 gas sorption, storage, and separation; 3,4 molecular magnetism5 and recognition; 6 and nonlinear optics. 7 While the synthesis of fascinating self-assembly metal-organic coordination polymers occurs via bridging ligand and also through weak noncovalent interactions, such as π − π stacking or hydrogen bonding, 8−20 the construction of metal-organic compounds mainly depends on the nature of the organic ligands and metal ions.
14p
langthannam
29-12-2021
11
0
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The adsorption capacity of CO2 and H2 in the absence and presence of water medium in MIL-88A was analyzed. We found that the magnitude of the CO2 capacity was many times higher than that of the H2 capacity, which led to rather high CO2/H2 selectivity.
13p
meyerowitz
25-12-2021
14
0
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The structural characteristics of NH2-MIL-88B(Fe) have exhibited an advantageous application potentialities in gas storage, separation and heterogeneous catalysis. This MOF is usually obtained by the hydrothermal synthesis in a Teflon-lined autoclave at high temperature (>150o C) under static conditions.
6p
viengland2711
23-07-2019
13
2
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