Heterogeneous catalysis

A metal-organic framework Cu2(NDC)2(DABCO) was synthesized from copper nitrate trihydrate, 2,6-Napthalenedicarboxylic acid (H2NDC), and 1,4-diazabicyclo[2.2.2]octane (DABCO) by solvothermal method. Its physicochemical properties were confirmed by several techniques such as X-ray powder diffraction (PXRD), Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM).

7p vikwong 29-09-2024 2 1   Download

In this research, the nanosized Fe2V4O13 complex oxide material was synthesized by the hydrothermal method. Its structure, morphology characterization, and other properties were determined using X-ray, SEM, EDX, and DTA-TG methods.

5p vikwong 29-09-2024 2 1   Download

Methods for using commercially available copper ferrite nanoparticles for organic transformations have witnessed emerging development. Herein we expand the application of such material for heterogeneously catalytic annulation of N,N-dimethylaniline and maleimides to yield tetrahydroquinolines.

4p vikwong 29-09-2024 3 1   Download

A copper-organic framework Cu2(BDC)2DABCO was synthesized, and used as a recyclable heterogeneous catalyst for C-N coupling reaction between benzamide and cyclohexane. 94% yield of N-cyclohexylbenzamide was achieved under the optimized condition. The copper-organic framework catalyst was truly heterogeneous and could be used at least 4 cycles without degradation of catalytic performance.

6p vikwong 29-09-2024 4 1   Download

The reaction parameters including catalyst concentrations, reaction temperatures, molar ratio of p-anisidine/2,5- hexadione, and solvents, were systematically investigated. Almost 100% conversion was achieved under the optimized reaction conditions. The reusability of MOF-118 catalyst was studied. Furthermore, we demonstrated that the functional groups on aryl amines have strongly effect on the reaction rate.

7p vikwong 29-09-2024 5 1   Download

In this study, we successfully synthesized a bimetallic metal-organic framework material Zn/Co-ZIF to start Peroxymonosulfate (PMS) for organic dye degradation in the water body. Material characterization was evaluated by advanced methods, such as XRD, FT-IR, SEM, EDX, and BET. The influence of different factors on methylene blue (MB) decomposition rate was investigated.

7p vikwong 29-09-2024 3 1   Download

The purpose of the thesis is to develop the novel and more effective strategies to furnish fluorine containing compounds employing readily, inexpensive and effective methods under heterogeneous transition metal catalysts.

29p extraenglish 26-05-2021 8 3   Download

A simple, efficient and general method for the synthesis of 4H-pyrans is established through a multi component cyclocondensation of aromatic aldehydes, malononitrile and ethyl acetoacetate or acetyl acetone using snail shell as a natural catalyst.

10p tocectocec 26-05-2020 22 2   Download

Wastewater of the dyeing unit of the Hanoi textile-dyeing Company (Hanosimex) was treated by coagulation method with the HBM/KT powder and by catalytic oxidation with the hydrogen peroxide (H2O2) over HBM/TB catalyst. HBM/KT coagulator and HBM/TB catalyst were prepared at the Laboratory of Surface Sciences and Catalysis, Institute of Chemistry, Vietnamese Academy of Science and Technology.

6p uocvong01 24-09-2015 53 4   Download

Petroleum mixtures consist primarily of relatively unreactive complex hydrocarbons covering a wide boiling range. Such mixtures are difficult to separate by most analytical techniques. Therefore, the petroleum industry has for many years played a leading role in the development of chromatographic methods of analysis. Since the last book specifically concerned with chromatographic analysis of petroleum appeared 15 years ago, numerous advances have been made including developments in liquid and supercritical fluid chromatography, ...

453p trua_nang 22-04-2013 110 15   Download