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Hydrazine reduction
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For the first time the synthesis of poly(N -vinyl-2-pyrrolidone)-stabilized cobalt-palladium nanoparticles by an easy method, their characterization, and their use as active catalysts for hydrogen release from hydrolysis of ammonia borane and hydrazine borane is reported here. The catalyst is prepared by simultaneous reduction of suitable cobalt and palladium ions by sodium borohydride in the presence of poly(N -vinyl-2-pyrrolidone) as a stabilizer. They are characterized by UV-Vis spectroscopy, TEM analysis, X-ray diffraction, and X-ray photoelectron spectroscopy.
12p
langthannam
29-12-2021
9
0
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The catalytic activity of 1,3,5-triazine-pentaethylenehexamine (TAPEHA) polymer-supported Pd nanoparticles was investigated in the reduction of nitro arenes to the corresponding amines by NaBH4 or N2H4.HO. Optimized reaction conditions for both systems were successfully tested on 20 nitroarenes with different characteristics. Considerably high yields (80%–98% in NaBH4 and 85%–98% in N2H4) were obtained in a short time and at ambient temperature.
9p
tudichquannguyet
29-11-2021
15
1
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Nickel catalysts supported on γ-Al2 O3 were synthesized in the presence of polyvinylpyrrolidone (PVP) using both alkaline polyol method and hydrazine reduction method while fixing the weight ratio of [(PVP)]/[Ni(CH3COO)2·4H2O] at 2. The effects of hydrazine [N2H5OH]/[Ni] and [NaOH]/[Ni] molar ratios on the structural properties of the catalysts were characterized by transmission electron microscopy (HRTEM) and by X-ray diffraction (XRD). The average of monodispersed Ni nanoparticles ranged between 8.0 and 13.0 nm.
19p
tudichquannguyet
29-11-2021
10
1
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Nickel nanostructures prepared by various methods have received considerable attentions due to their numerous applications. In this study, one-dimensional nickel nanowires (NiNWs) were synthesized by the reduction of nickel (II) chloride in polyol medium. Polyvinylpyrrolidone (PVP) served as the surfactant and hydrazine hydrate was used as the reductant.
8p
vidonut2711
08-11-2019
8
0
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Synthesis of the copper nanoparticles colloidal solutions by chemical reduction method with various precursors including copper oxalate, CuCl2, CuSO4, Cu(NO3)2 with hydrazine hydrate reducing agent, NaBH4; solvent glycerin and water, PVA and PVP protection, dispersants and protective agents: including trisodium citrate, ascorbic acid, CTAB.
26p
change05
10-06-2016
46
3
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Tuyển tập báo cáo các nghiên cứu khoa học quốc tế ngành hóa học dành cho các bạn yêu hóa học tham khảo đề tài: ITemplate-free Synthesis of One-dimensional Cobalt Nanostructures by Hydrazine Reduction Route
5p
dauphong14
13-02-2012
39
4
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