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Mechanically plausible
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The efficient synthesis of 12-substituted-3,4,4a,5,12,12a-hexahydrobenzo[b]acridine-1,6,11(2H)-triones starting from 2-amino-1,4-naphthoquinone, 1,3-cyclohexanedione, and different (hetero)aromatic aldehydes was developed. These reactions were carried out in acetic acid under microwave irradiation in the presence of p-toluenesulfonic acid as catalyst. The structure of the newly synthesized compounds were confirmed employing spectroscopic data as well as elemental analysis. The plausible mechanism of these three-component domino reactions was also described.
7p
dianmotminh02
03-05-2024
4
1
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Ebook "The quantum gamble" presents the history of quantum theory together with open questions and remaining problems in terms of the plausibility of quantum chemistry and physics. It also provides insights into the theory of matter-wave mechanics. The content is aimed at students and lecturers in chemistry, physics and the philosophy of science.
177p
tracanhphuonghoa1007
22-04-2024
3
3
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A density functional theory (DFT) study on the hydroxyl radical scavenging properties of Kinsenoside originated from Anoectochilus roxburghii is presented. Two mechanisms, single electron transfer (SET) and hydrogen atom transfer (HAT) are considered. The thermochemical results demonstrate that the SET mechanism is not plausible to occur.
5p
vichristinelagarde
04-07-2022
5
1
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The reactivity of some 1,2-alkadienephosphonates towards phenyltelluryl halides was investigated. A plausible mechanism of the reaction is discussed. Consequently, many attempts for their synthesis have been made. One of the easiest and most fruitful methods for the synthesis of these derivatives is electrophile-induced heterocyclization of 1,2-alkadienephosphonates.
6p
langthannam
29-12-2021
14
0
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Olivine LiFePO4 has been studied for more than a decade as a promising cathode material for rechargeable lithium batteries. However, the low electric conductivity and tap density still hinder its large-scale commercialization. Micro-sized LiFePO4 is prepared by an optimized hydrothermal method in this paper. The influence of postannealing on the physicochemical properties of LiFePO4 and FePO4 is investigated to understand the plausible mechanism for performance degradation.
13p
langthannam
29-12-2021
6
0
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Post transcriptional gene regulation in wheat cultivars caused by boron (B) toxicity has not been reported to date. In this study, two wheat cultivars Bolal-2973 (B-tolerant) and Atay-85 (B-sensitive) were compared with regard to the transcriptional regulation of miR319, miR172 and miR398 and their plausible target genes in order to address differences in their performances under high B levels. The expression levels of Cu/ZnSOD gene were found to be greater in Atay exposed to toxic B compared to Bolal, as verified by stable expression level of miR398.
23p
hanthienngao
30-11-2021
12
1
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Milk yield for Holstein cows has doubled over five decades due to genetic selection and changes to management, but the molecular mechanisms that facilitated this increase are mostly unknown. Epigenetic modifications to the cattle genome are a plausible molecular mechanism to cause variation in milk yield and our objective was to describe genome-wide DNA methylation patterns in peripheral blood mononuclear cells (PBMC) from mature Holstein dairy cows with variable milk yield.
12p
vitzuyu2711
29-09-2021
7
1
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It is mechanically plausible that osteoporosis leads to more severe peripheral fractures, but studies investigating associations between BMD and radiographically verified complexity of distal radius fractures are scarce. This study aims to study the association between osteoporosis, as well as other risk factors for fracture, and the AO classification of distal radius fractures.
5p
vimariana2711
22-12-2020
5
0
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Coilia nasus oogenesis/spawning migration is a well-defined synchronous arrangement process. DnaJs are indispensable molecular chaperones for oogenesis process. However, how DnaJs involved the anadromous spawning migration mechanism is outstanding and plausible.
11p
viwyoming2711
16-12-2020
10
1
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Continuous surveillance for intussusception (IS) is important for monitoring the safety of secondgeneration rotavirus vaccines. The present study aimed to assess the incidence of IS in Singaporean children aged < 2 years.
7p
vinatri2711
29-02-2020
13
0
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The oxidation reaction of triiodide, I3 −, by chlorate is investigated in a slightly acidic and neutral media. The reaction was verified and monitored both potentiometrically and spectrophotometrically. Generally, a slow linear decay preceded by an induction period was observed for the triiodide concentration following the addition of chlorate. The induction period is likely to be related to the time required for the generation of suitable concentrations of plausible intermediates (HIO and HIO2), which are assumed to auto-catalyse the reaction.
6p
kethamoi1
20-11-2019
7
0
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In search of new ways to improve catalyst design, the current research focused on using quantum mechanical descriptors to investigate the effect of proline as a catalyst for mechanism and rate of asymmetric aldol reaction. A plausible mechanism of reaction between acetone and 4-nitrobenzaldehyde in acetone medium was developed using highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energies calculated via density functional theory (DFT) at the 6-31G⁄/ B3LYP level of theory.
9p
trinhthamhodang1
14-11-2019
18
1
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Polymer modified alkali treated jute fibre as a reinforcing agent, substantially improves the physical and mechanical properties of cement mortar with a mix design cement:sand:fibre:water::1:3:0.01:0.6. The workability of the mortar is found to increase systematically from 155 ± 5 mm (control mortar) to 167 ± 8 mm (0.2050% polymer modified mortar). The density of the mortar is increased from 2092 kg/ m3 to 2136 kg/m3 with a concomitant reduction of both water absorption and apparent porosity. Optimal polymer content in emulsion (0.
9p
christian2605
11-10-2019
12
2
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This result indicates that the B-exclusion mechanism is not involved in differential expression of B tolerance within 70 durum wheat genotypes. It seems very likely that the internal mechanisms (e.g., adsorption to cell walls and compartementation of B in vacuoles) could be a more plausible explanation for B tolerance in the durum wheats tested in the present study.
10p
aquaman27
15-01-2019
7
1
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The photocatalytic oxidation of reactive blue 2 and reactive red 120 has been studied by using TiO2 Degussa P25 as catalyst and UV-light. The formation of intermediate molecules could be predicted on the basic of point charge calculations on all the individual atoms of the dyes. The agreement between calculations from quantum theory and the results of experiments was the background to establish a pathway for degradation of reactive dyes. A plausible mechanism of dye photodegradations is discussed.
6p
uocvong03
24-09-2015
83
3
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The timing of monthly bill payments could explain the pattern we observe, if the timing happens to coincide with payday for most households. To the extent that the timing of bill payments is non-discretionary, this explanation implies that the decline in spending cannot be used to infer household preferences for timing of consumption.
76p
bin_pham
06-02-2013
47
4
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Risk and return measures for models of funds are typically statistics such as mean and standard deviation. A straightforward way to get a commensurable set of measures is to choose only statistics measured in the same units as the data. Often the literature uses statistics such as variance, semivariance, skewness and kurtosis not in the same units (Wilkens and Zhu, 2001; Gregoriou et al., 2005b; Nguyen-Thi-Thanh, 2006). There are several plausible explanations.
24p
thangbienthai
20-11-2012
55
3
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Environmental Chemistry is a relatively young science. Interest in this subject, however, is growing very rapidly and, although no agreement has been reached as yet about the exact content and limits of this interdisciplinary discipline, there appears to be increasing interest in seeing environmental topics which are based on chemistry embodied in this subject. One of the first objectives of Environmental Chemistry must be the study of the environment and of natural chemical processes which occur in the environment.
338p
nhulan0908
29-09-2012
67
12
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Studies in the past quarter of century have established a role for lymphocytes in the pathogenesis of immune-mediated glomerular diseases. CD4- expressing T helper cells are a subgroup of T lymphocytes that provide help for immunoglobulin production and direct cellular immune mechanisms through activation of effector cells, such as macrophages. The role of T helper cells is variable depending on the nature of disease, and differential activation of T helper cell subsets has been proposed as one of the plausible explanations for the diversity of injury in glomerular diseases....
336p
kmkmkmkmkm
08-09-2012
52
5
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