Sm3+ complex containing benzoyltrifluoroacetone
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The synthesis, structure, and luminescent properties of a samarium(III) complex (A2) containing benzoyltrifluoroacetone (HTFPB) and 1,2-bis[(anthracen-9-ylmethyl)amino]ethane (BAAE2) ligands are herein reported. The structure of A2 has been elucidated by infrared spectroscopy and single crystal X-ray diffraction. X-ray crystallographic analysis demonstrated that A2 has a mononuclear structure with a formula of Sm(TFPB)3 (BAAE2) in which Sm3+ ion is coordinated to six O-atoms from three TFPB ligands and two N-atoms from one ancillary ligand (BAAE2).
5p nguaconbaynhay12 13-06-2021 11 1 Download