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Synthesis and tautomerism
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New azo dyes bearing 2-pyridone and benzimidazole moieties were prepared using diazotization of 4-(1Hbenzo[d]imidazol-2-yl)aniline and coupling of the obtained diazonium salt with substituted 3-cyano-2-pyridones. Obtained compounds were characterized via UV-Vis, FT-IR, and 1H and 13C NMR spectroscopy as well as by elemental analysis data. The UV-Vis spectra of the synthesized dyes were measured in thirteen solvents of different properties at room temperature. Solvatochromism and tautomerism of novel azo dyes were discussed.
12p
tudichquannguyet
29-11-2021
11
0
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Two new azo-Schiff base receptors (L1 and L2) containing azo and azomethine groups with a conjugated group (benzyl ring of anthranilic acid, in L1) and electron-donating group (alkyl chain of hexanoic acid, in L2) were synthesized and characterized. Azo-hydrazone/phenol-keto tautomerism and solvatochromism were investigated. Studying their sensing ability towards cations (Co2+, Cu2+, Zn2+, Ni2+, Pb2+, Cd2+, Mn2+, Fe3+, Cr3+, and Al3+), high sensitivity and selectivity were recorded for Fe3+ by naked eye and UV-Vis spectra in DMF-aqueous HEPES buffer (v:v, 1:1, pH 6.8).
34p
tudichquannguyet
29-11-2021
22
1
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This review summarizes results from the literature concerning synthesis and azo-hydrazone tautomerism of arylazo- and hetarylazo-derivatives of various bi- and tri-heterocycles reported by us and other research groups from 1981 to mid 2009.
36p
kethamoi1
20-11-2019
11
2
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