Transition metals

The replacement of noble metals in homogeneous catalysts for the current CO2 hydrogenation reaction with 3D transition metals (Fe, Co, Ni and Mn), with lower costs, have attracted a great attention of many research groups to the interconversion of chemical and electrical energy, like CO2 and H2.

5p vikwong 29-09-2024 3 2   Download

In this article, the results of the research on organic pollutant treatment in the wastewater of printing processes on fabric by H2O2 under the catalytic role of the complex between ion Ni2+ and Citric acid (H4L) were presented.

5p vikwong 29-09-2024 3 1   Download

It can be seen that the objects of wastewater that need to be treated are quite diverse in types and complex in terms of reaction mechanisms. The methods mainly focus on the treatment of toxic organic compounds, especially phenols or plant protection agents in industrial wastewater, paper industry, food production, textile industry, printing industry.

6p vikwong 29-09-2024 4 0   Download

A series of Cu(II), Co(II), and Zn(II), mononuclear Schiff base complexes were studied and characterized by DFT calculations. The ligand was derived from the experiment of condensing 5-acetyl-4-hydroxy-2H-1,3-thiazine-2,6(3H)- dione with o-phenylenediamine.

5p vikwong 29-09-2024 1 1   Download

This tactic appears to be the first method to use a first-row transition metal to promote the synthesis of 2-aryl-4-quinazolinones from commercially available 2-nitrobenzonitriles.

5p vikwong 29-09-2024 2 1   Download

This work investigated the modification of MnOx catalysts by doping various metals (e.g., Cu) and supporting them on cordierite honeycomb ceramics using the impregnation method. The catalysts were characterized by BET, XRD, SEM-EDX, and H2-TPR techniques. The Cu1Mn2Ox catalyst exhibited the best catalytic performance, achieving complete oxidation of benzene and toluene at 275°C with a WHSV of 18,000 mL/(g·h).

6p vikwong 29-09-2024 3 1   Download

This modeling is performed on an experimental data set of complexes, where the metal ions of these complexes include transition ion metals and lanthanide ion metals. We use these models to develop a series of new thiosemicarbazone and their complexes; simultaneously, the complexes are worked out the stability constants from the novel models.

9p dianmotminh02 03-05-2024 7 2   Download

In recent times many research activities have been carried out to prove the metal ion detection ability of Schiff bases. [13,14] In the present study, a new Schiff base has been synthesized from 5-bromo-2- hydroxybenzaldehyde and naphthalene-1,8-diamine and it is complexated with Co(II), Ni(II), Cu(II) and Zn(II) ions. The biological application of all the compounds has been analyzed and metal ions recognition property of the Schiff base has also been studied.

16p dianmotminh02 03-05-2024 8 2   Download

Exciton hai chiều trong từ trường là bài toán quan trọng cho việc trích xuất các thông tin cấu trúc vật liệu đơn lớp TMD (Transition Metal Dichalcogenides). Bài viết trình bày tổng quát lại lí thuyết nhiễu loạn. Sau đó, sự hội tụ của nghiệm bổ chính bậc cao được nghiên cứu với từ trường lên tới 120 Tesla.

12p vithales 19-04-2022 22 2   Download

The purpose of the thesis research: Synthesis of new complexes of platinum and rare-earth elements containing quinoline's derivatives that are resistant to cancer cells, high antimicrobial activity or good fluorescence.

27p tunelove 10-06-2021 21 4   Download

Research purpose: Using computational chemistry methods to study the mechanism of hydrogenation CO on the transition metal catalyst systems of Ni, Cu, Co, bimetallic catalysts NiCu, CoCu and catalytic systems bearing cluster on oxide carriers: MgO, Al2O3 and activated carbon (AC); compare and clarify the role of catalyst centers in single or bimetallic catalyst systems; clarifies the role of carriers (MgO, Al2O3 and AC) in the hydrogenation of CO.

27p thebadguys 08-06-2021 26 4   Download

The purpose of the thesis is to develop the novel and more effective strategies to furnish fluorine containing compounds employing readily, inexpensive and effective methods under heterogeneous transition metal catalysts.

29p extraenglish 26-05-2021 8 3   Download

An examination of the first-row-transition-metal-doped boron clusters, B14M (M = Sc, Ti, V, Cr, Mn, Fe, Co, Ni, and Cu) in the neutral state, is carried out using DFT quantum chemical calculations. The lowest-energy equilibrium structures of the clusters considered are identified at the TPSSh/ 6- 311+G(d) level. The structural patterns of doped species evolve from exohedrally capped quasi-planar structure B14 to endohedrally doped double-ring tubular when M is from Sc to Cu.

7p nguaconbaynhay9 03-12-2020 13 1   Download

We obtained the analytic expressions of the specific heat at constant volume of metals which are dependent on the value of q-deformed parameters. Results calculated for the specific heat at constant volume for some kinds of alkali and transition metals show good agreement with those obtained by other theories and in experiments as well.

8p tamynhan8 04-11-2020 6 2   Download

Influence of substitution of 3d metals for Mn on properties of La0.67Ca0.33Mn0.9 TM0.1O3 (TM = Fe, Co, Ni) compounds was studied. Ferromagnetic – paramagnetic and metals – insulator transitions were significantly affected by Mn-site substitution. However, no observable difference was found in their crystal structure from X-ray diffraction analysis. At room temperature the structure characterization of these compounds gave the single phase and structure is the distortion orthorhombic cell with space group symmetry Pnma.

12p 12120609 01-06-2020 13 2   Download

A new series of transition metal complexes of Co(III), Ni(II) and VO(IV) was synthesized with the bidentate Schiff base ligand (HL) derived from the condensation of 2-amino-3-benzyloxypyridine and 5-bromo salicylaldehyde.

14p tocectocec 25-05-2020 23 2   Download

The thesis with the objective of researching to assess the biodegradability (including decomposition process and decomposition in soil environment) of polyethylene film containing additives promoting oxidation is Fe stearate salts (Fe). III), Co (II) and Mn (II).

27p xacxuoc4321 11-07-2019 16 2   Download

2D nanomaterials such as graphene and transition metal dichal  cogenides (TMDCS) have shown outstanding potential in many fields such as fl exible electronics, sensing and optics due to their desirable physical and structural properties. High quality black phosphorus atomic layers by liquid phase exfoliation include Experimental Section; Supporting Information and Acknowledgements.

6p dangthaitrieu 11-05-2015 35 4   Download

The annual production of various polymers can be measured only in billion tons of which polyolefins alone figure around 100 million tons per year. In addition to radical and ionic polymerization, a large part of this huge amount is manufactured by coordination polymerization technology. The most important Ziegler-Natta, chromium- and metallocene-based catalysts, however, contain early transition metals which are too oxophilic to be used in aqueous media.

19p boyminsk 10-06-2010 153 16   Download

Solubility of the catalysts in water is determined by their overall hydrophilic nature which may arise either as a consequence of the charge of the complex ion as a whole, or may be due to the good solubility of the ligands. Although transition metal complexes with small ionic ligands, such as halides, pseudohalides or simple carboxylates can be useful for specific reactions the possibility of the variation of such ligands is very limited. As in organometallic catalysis in general, phosphines play a leading role in aqueous organometallic catalysis (AOC), too.

0p boyminsk 10-06-2010 103 15   Download