Dinuclear complexes
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The following silver and copper complexes in which quinine is coordinated via the two possible donor atoms was prepared and characterized. Coordination of quinine via the hydroxyl oxygen and quinoline nitrogen is observed in C20H25N2O2Cu2(SO4)2.6H2O and C20H25N2O2Ag2(SO4). The existence of the proton at the coordinated hydroxyl oxygen is also observed in these complexes. The coordination mode and the conformation of quinine can be derived from IR and Raman spectra and by using NMR techniques.
5p uocvong04 24-09-2015 38 3 Download
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Mitochondrial calcium overload has been implicated in the irreversible damage of reperfused heart. Accordingly, we studied the effect of an oxy-gen-bridged dinuclear ruthenium amine complex (Ru360 ), which is a select-ive and potent mitochondrial calcium uniporter blocker, on mitochondrial dysfunction and on the matrix free-calcium concentration in mitochondria isolated from reperfused rat hearts.
12p fptmusic 11-04-2013 51 2 Download