Heterogeneous catalyst
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A metal-organic framework Cu2(NDC)2(DABCO) was synthesized from copper nitrate trihydrate, 2,6-Napthalenedicarboxylic acid (H2NDC), and 1,4-diazabicyclo[2.2.2]octane (DABCO) by solvothermal method. Its physicochemical properties were confirmed by several techniques such as X-ray powder diffraction (PXRD), Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM).
7p vikwong 29-09-2024 2 1 Download
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In this research, the nanosized Fe2V4O13 complex oxide material was synthesized by the hydrothermal method. Its structure, morphology characterization, and other properties were determined using X-ray, SEM, EDX, and DTA-TG methods.
5p vikwong 29-09-2024 2 1 Download
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A copper-organic framework Cu2(BDC)2DABCO was synthesized, and used as a recyclable heterogeneous catalyst for C-N coupling reaction between benzamide and cyclohexane. 94% yield of N-cyclohexylbenzamide was achieved under the optimized condition. The copper-organic framework catalyst was truly heterogeneous and could be used at least 4 cycles without degradation of catalytic performance.
6p vikwong 29-09-2024 4 1 Download
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The reaction parameters including catalyst concentrations, reaction temperatures, molar ratio of p-anisidine/2,5- hexadione, and solvents, were systematically investigated. Almost 100% conversion was achieved under the optimized reaction conditions. The reusability of MOF-118 catalyst was studied. Furthermore, we demonstrated that the functional groups on aryl amines have strongly effect on the reaction rate.
7p vikwong 29-09-2024 6 1 Download
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In this study, we successfully synthesized a bimetallic metal-organic framework material Zn/Co-ZIF to start Peroxymonosulfate (PMS) for organic dye degradation in the water body. Material characterization was evaluated by advanced methods, such as XRD, FT-IR, SEM, EDX, and BET. The influence of different factors on methylene blue (MB) decomposition rate was investigated.
7p vikwong 29-09-2024 3 1 Download
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The purpose of the thesis is to develop the novel and more effective strategies to furnish fluorine containing compounds employing readily, inexpensive and effective methods under heterogeneous transition metal catalysts.
29p extraenglish 26-05-2021 8 3 Download
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In this study, pellets of iron alumina pillared bentonite (PFeAPB) were prepared by dispersing iron ions on alumina pillared bentonite pellet. Catalyst activity and lifetime were investigated via efficiencies of Methyl Orange (MO) decolorization and Chemical Oxygen Demand (COD) removal, a typical dye type of textile wastewater. Characteristics of the PFeAPB catalyst were examined by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) surface area, and X-ray fluorescence (XRF).
9p larachdumlanat127 02-01-2021 20 2 Download
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TiO2-Graphene Oxide-Hemin (TiO2/GO/Hemin) ternary composite hybrid material was prepared by the sol-gel method and used as a heterogeneous catalyst for the photocatalytic degradation of organic contaminants. The catalytic activity of GO-TiO2-Hemin was evaluated by the degradation of Rhodamine B (RhB) under the UV-visible light irradiation and in the presence of hydrogen peroxide.
9p tamynhan4 06-09-2020 18 3 Download
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A simple, efficient and general method for the synthesis of 4H-pyrans is established through a multi component cyclocondensation of aromatic aldehydes, malononitrile and ethyl acetoacetate or acetyl acetone using snail shell as a natural catalyst.
10p tocectocec 26-05-2020 23 2 Download
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The work has been carried out under thermal solvent free conditions. Mg/Fe = 3 hydrotalcite heterogeneous solid catalyst offers simple means of recovery and the isolated catalyst was reused for number of times without significant loss of catalytic activity.
14p tocectocec 25-05-2020 6 2 Download
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In this article, magnetically nanoparticles (MNPs) of CuFe2O4 were prepared and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction and transmission electron microscopy techniques.
10p tocectocec 25-05-2020 16 0 Download
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Objectives of thesis: Study on phenol treatment in water by ozonation process combined with catalysts. An empirical kinetic model and one quadratic regression equations were built based on experimental data for destroying phenol by heterogeneous catalytic ozonation process with response variables (initial pH, ozone concentration, catalyst concentration and reaction time). Application of phenol treatment in coking wastewater.
29p xacxuoc4321 08-07-2019 18 4 Download
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Wastewater of the dyeing unit of the Hanoi textile-dyeing Company (Hanosimex) was treated by coagulation method with the HBM/KT powder and by catalytic oxidation with the hydrogen peroxide (H2O2) over HBM/TB catalyst. HBM/KT coagulator and HBM/TB catalyst were prepared at the Laboratory of Surface Sciences and Catalysis, Institute of Chemistry, Vietnamese Academy of Science and Technology.
6p uocvong01 24-09-2015 53 4 Download
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Chemical reaction engineering (reaction engineering or reactor engineering) is a specialty in chemical engineering or industrial chemistry dealing with chemical reactors. Frequently the term relates specifically to catalytic reaction systems where either a homogeneous or heterogeneous catalyst is present in the reactor.
146p 61204392 22-10-2014 80 15 Download
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Preparation, characterization and application of heterogeneous solid base catalyst for biodiesel production from soybean oil has many contents: Preparation of catalyst, haracterization of the catalys, ransesterification of soybean oil and chemicalanalyses, creening of catalyst, atalyst characterizations, fluence of the transesterification reactionconditions,...
9p cscpubka 05-05-2014 113 1 Download