Temperature the structure characterization

Two ionic liquids named triethyl ammonium oleate ([TEA][Oleate] and triethyl ammonium stearate ([TEA][Stearate]) were synthesized from triethyl amine and oleic/stearic acids in water and in ethanol solvents. The synthesized ionic liquids were characterized by FT-IR and NMR spectra to confirm their structure. The influence of some parameters such as structure of ionic liquid anion, solvent, reaction time, reaction temperature, and acid/amine molar ratio on the synthesis processes of triethyl ammonium oleate and triethyl ammonium stearate was investigated.

6p vikwong 29-09-2024 3 1   Download

In this study, Zinc oxide (ZnO) nanoparticles with a size of about 50 - 70 nm were green-synthesized using tea leaves and ZnO/Polypyrrole (ZnO/Ppy) nanocomposites were obtained by ultrasonic-assisted chemical polymerization method using pyrrole monomer and the nanoparticles. The characterization of the materials is conducted using several analytical techniques, including Field Emission Scanning Electron Microscopy (FESEM) and X-Ray Diffraction (XRD) and Ultraviolet visible spectrum (UV-Vis).

11p xuanphongdacy06 18-09-2024 2 1   Download

The focus of this study is to investigate its optical and conductive properties under different conditions of doping environments, temperature and polymerization conditions. Optical characterization technique such as UV-Visible spectroscopy is developed to carry out the investigation. The developed nanofibers have been demonstrated to possess optical and conductive properties to be dependent on doping variables. Study of these optical properties could prove very useful in the development of electrochromic devices and gas sensors.

103p runthenight07 01-03-2023 7 3   Download

In the current context of eco-pollution, the substitute of conventional plastics with bioplastics is a big confront. On account of that, a non-growth associated PHB production study was conducted using Zobellella species under submerged fermentation process. As a result, Zobellella species showed the ability to accumulate 2.2g/L of PHB at pH 8. 0, temperature 37oC, salt concentration 2% in modified growth medium containing vitamins. Then, primary structural characterization of extracted polymer was conducted by FTIR analysis. The high intense peak was obtained at 1720.

7p nguaconbaynhay6 24-06-2020 38 3   Download

Analytical expressions for the anharmonic effective potential, local force constant, Displacement-displacement Correlation Function (DCF) CR and Debye-Waller factor described by the Mean Square Relative Displacement (MSRD) σ2 and by the Mean Square Displacement (MSD) u2of bcc crystals in the X-ray Absorption Fine Structure (XAFS) have been derived. The effective interatomic potential of the system has been considered by taking into account the influences of nearest atomic neighbors, and it contains the Morse potential characterizing the interaction of each pair of atoms.

8p 12120609 01-06-2020 14 2   Download

Influence of substitution of 3d metals for Mn on properties of La0.67Ca0.33Mn0.9 TM0.1O3 (TM = Fe, Co, Ni) compounds was studied. Ferromagnetic – paramagnetic and metals – insulator transitions were significantly affected by Mn-site substitution. However, no observable difference was found in their crystal structure from X-ray diffraction analysis. At room temperature the structure characterization of these compounds gave the single phase and structure is the distortion orthorhombic cell with space group symmetry Pnma.

12p 12120609 01-06-2020 13 2   Download

In this investigation, neodymium orthoferrite (NdFeO3) nanoparticles has been synthesized through ultrasonic method in the presence of octanoic acid as surfactant. This method comparing to the other methods is very fast and it does not need high temperatures during the reaction.

8p tocectocec 25-05-2020 4 1   Download

Porous hydroxyapatite ceramic was synthesized by solid phase method using Ca(OH)2 and Ca3(PO4)2 at the temperature interval 200 - 350o C. The samples, after pelleting and sintering, were characterized by X-ray diffractometry (XRD), Fourier transform infra-red spectroscopy (FTIR), scanning electron microscopy (SEM) and thermal gravimetric analysis (TGA). Porous structure of hydroxyapatite was obtained with the 42 – 55% porosity.

5p uocvong01 24-09-2015 117 17   Download

A recombinant lipase cloned from Pseudomonas fragi strain IFO 3458 (PFL) was found to retain significant activity at low temperature. In an attempt to elucidate the structural basis of this behaviour, a model of its three-dimensional structure was built by homology and compared with homologous mesophilic lipases, i.e. the Pseudomonas aeruginosa lipase (45% sequence identity) and Burkholderia cepacia lipase (38%).

8p system191 01-06-2013 48 4   Download

Antifreeze proteins (AFPs) are produced by several cold-water fish species. They depress physiological freezing temperatures by inhibiting growth of ice crystals and, in so doing, permit the survival of these fish in seawater cooler than their normal freezing temperatures. The type II AFP from rainbow smelt (Osmerus mordax), which is a member of the C-type lectin superfamily, was characterized in terms of its Ca2+-binding quaternary structure and the role of its single N-linked oligosaccharide....

8p research12 01-06-2013 40 4   Download

The nitrilase AtNIT1 fromArabidopsis thalianawas over-expressed inEscherichia coliwith an N-terminal His6tag and puri®ed by zinc chelate anity chromatography in a single step almost to homogeneity in a 68% yield with a speci®c activity of 34.1 Uámg )1 . The native enzyme (450 kDa) consists of 11±13 subunits (38 kDa). The temperature optimum was determined to be 35°C, and a pH optimum of 9 was found.

8p research12 23-04-2013 27 2   Download

The interaction of bacterial endotoxins [lipopolysaccharide (LPS) and the
endotoxic principle lipid A], with high-den-sity lipoprotein (HDL) from serum was investigated with a variety of physical techniques and biological assays. HDL exhibited an increase in the gel to liquid crystalline phase transition temperature Tc and a rigidification of the acyl chains of the endotoxins as measured by Fourier-transform infrared spectroscopy and differential scanningcalorimetry.

10p tumor12 22-04-2013 38 3   Download

Enzymes from psychrophiles show higher catalytic efficiency in the 0–20C temperature range and often lower thermostability in comparison with meso⁄thermophilic homologs. Physical and chemical characterization of these enzymes is currently underway in order to understand the molecular basis of cold adaptation.

14p media19 04-03-2013 24 1   Download