Catalytic performance

The results showed that GdFeO3 photocatalyst had a good performance under visible light irradiation. The remarkable enhancement photo-Fenton catalytic activity of GdFeO3 material could be attributed to its small particle size and narrow band gap energy.

6p vikwong 29-09-2024 2 1   Download

A copper-organic framework Cu2(BDC)2DABCO was synthesized, and used as a recyclable heterogeneous catalyst for C-N coupling reaction between benzamide and cyclohexane. 94% yield of N-cyclohexylbenzamide was achieved under the optimized condition. The copper-organic framework catalyst was truly heterogeneous and could be used at least 4 cycles without degradation of catalytic performance.

6p vikwong 29-09-2024 4 1   Download

The higher catalytic performance of CuMnOx than MnO2, CuO because of its higher specific surface area and its lower reduction temperature. The results also implied that the interaction between Cu and Mn could improve the reduction capacity of CuMnOx catalyst. In summary, the CuMnOx catalyst is a promising catalyst for toluene treatment.

7p vikwong 29-09-2024 4 1   Download

he catalytic dehydration of ethanol is a potential alternative route to synthesize ethylene apart from the traditional method which depends on fossil fuels. This report successfully prepared modified ZSM-5 with mesopores using desilication methods to enhance ethanol catalytic dehydration performance and ethylene production at lower temperature.

5p vikwong 29-09-2024 3 1   Download

This work investigated the modification of MnOx catalysts by doping various metals (e.g., Cu) and supporting them on cordierite honeycomb ceramics using the impregnation method. The catalysts were characterized by BET, XRD, SEM-EDX, and H2-TPR techniques. The Cu1Mn2Ox catalyst exhibited the best catalytic performance, achieving complete oxidation of benzene and toluene at 275°C with a WHSV of 18,000 mL/(g·h).

6p vikwong 29-09-2024 3 1   Download

The results show that the cerium oxide spherical nanoparticles built from primary nanoparticles with the average size of ~5 nm, exhibited dispersion and uniform size and shapes with their average particle diameter of ~50 nm in size. With such a good morphology, CeO2 material possessed good catalytic activity for the decomposition of methylene blue (MB), in which the material was synthesized at a hydrothermal temperature of 80 oC (CeO2-80) for the best MB decomposition performance.

10p meyerowitz 25-12-2021 5 0   Download

In Vietnam, currently the study of fuel cells is almost neglected and there is very little fundamental research on this issue. The research on fuel cells of our country is at innitial stage, mainly researching catalytic material in the laboratory and almost has not research in the technology of manufacturing fuel cell (stack).

28p larachdumlanat129 20-01-2021 19 5   Download

The effects of addition of alumina to the matrices of cracking catalysts containing different types of zeolite Y, on their cracking performance, were investigated using a micro activity test and two different feed oils.

13p tuananhhumg 04-11-2013 50 3   Download

The sulfonephthalein indicator, phenol red, exhibits an unusually slow rate of oxidation by laccase fromPolipo-rus pinsitus, in spite of the fact that it is a phenol and therefore a natural substrate for this phenoloxidase enzyme. Nevertheless, after prolonged exposure to laccase (24 h) phenol red is oxidized by more than 90%.

7p tumor12 20-04-2013 40 2   Download

Proteolysis of single polypeptide mammalian purple acid phosphatases (PAPs) results in the loss of an interaction between the loop residue Asp146 and the active site residues Asn91 and⁄or His92. While Asn91 is a ligand to the divalent metal of the mixed-valent di-iron center, the role of His92 in the catalytic mechanism is unknown. Site-directed mutagenesis of His92 was performed to examine the role of this residue in single polypep-tide PAP.

10p awards 06-04-2013 42 3   Download

Fifty-nine amino acid sequences belonging to family 57 (GH-57) of the glycoside hydrolases were collected using the CAZy server, Pfamdatabase andBLASTtools. Owing to the sequence heterogeneity of the GH-57 members, sequence alignments were performed using mainly manual methods. Likewise, five conserved regions were identified, which are postulated to be GH-57 consensus motifs.

10p dell39 03-04-2013 32 2   Download

Recent studies on type II thioesterases (TEIIs) involved in microbial secondary metabolism described a role for these enzymes in the removal of short acyl-S- phosphopantetheine intermediates from misprimed holo-(acyl carrier proteins) and holo-(peptidyl carrier proteins) of polyketide synthases and nonribosomal peptide synthetases.

10p dell39 03-04-2013 53 4   Download

The catalytic module ofHypocrea jecorina(previously Trichoderma reesei) Cel7B was homologously expressed by transformation of strain QM9414. Post-translational modi-fications in purified Cel7B preparations were analysed by enzymatic digestions, high performance chromatography, mass spectrometry and site-directed mutagenesis. Of the five potential sites found in the wild-type enzyme, only Asn56 and Asn182 were found to be N-glycosylated.

11p dell39 03-04-2013 44 5   Download

The catalytic reaction mechanism and binding of substrates was investi-gated for the multisubstrateDrosophila melanogasterdeoxyribonucleoside kinase. Mutation of E52 to D, Q and H plus mutations of R105 to K and H were performed to investigate the proposed catalytic reaction mech-anism, in which E52 acts as an initiating base and R105 is thought to sta-bilize the transition state of the reaction.

10p galaxyss3 21-03-2013 31 5   Download

Cell survival depends not only on the ability to repair damaged DNA but also on the capability to perform DNA replication on unrepaired or imperfect templates. Crucial to this process are specialized DNA polym-erases belonging to the Y family. These enzymes share a similar catalytic fold in their N-terminal region, and most of them have a less-well-con-served C-terminus which is not required for catalytic activity.

11p galaxyss3 19-03-2013 36 3   Download

The direct conversion of plant cell wall polysaccharides into soluble sugars is one of the most important reactions on earth, and is performed by cer-tain microorganisms such as Clostridium thermocellum(Ct). These organ-isms produce extracellular multi-subunit complexes (i.e. cellulosomes) comprising a consortium of enzymes, which contain noncatalytic carbohy-drate-binding modules (CBM) that increase the activity of the catalytic module.

12p media19 06-03-2013 45 4   Download

An important aspect of catalysis performed by cholesterol oxidase (3b-hy-droxysteroid oxidase) concerns the nature of its association with the lipid bilayer that contains the sterol substrate. Efficient catalytic turnover is affected by the association of the protein with the membrane as well as the solubility of the substrate in the lipid bilayer.

13p viettel02 20-02-2013 35 3   Download

Tuyển tập các báo cáo nghiên cứu khoa học trên tạp chí khoa học vật lý quốc tế đề tài: Synthesis, Characterisation and Catalytic Performance of Porous Nafion Resin/Silica Nanocomposites for Esterification of Lauric Acid and Methanol

14p hoami_266 15-09-2011 56 7   Download